Modeling Air Emissions of Organic Compounds from Contaminated Sediments and Dredged Materials title change in last year to "Long-term Release of Pollutants from Contaminated Sediment Dredged Material"| Research Project Database | NCER | ORD

Modeling Air Emissions of Organic Compounds from Contaminated Sediments and Dredged Materials title change in last year to "Long-term Release of Pollutants from Contaminated Sediment Dredged Material"

EPA Grant Number: R825513C017
Subproject: this is subproject number 017 , established and managed by the Center Director under grant R825513
(EPA does not fund or establish subprojects; EPA awards and manages the overall grant for this center).
Center: HSRC (1989) - South and Southwest HSRC
Center Director: D. Reible, Danny
Title: Modeling Air Emissions of Organic Compounds from Contaminated Sediments and Dredged Materials title change in last year to "Long-term Release of Pollutants from Contaminated Sediment Dredged Material"
Investigators: Valsaraj, Kalliat T. , Brannon, J. M. , D. Reible, Danny , Gulliver, John S. , Meyers, T. E. , Price, C. B. , Thibodeaux, Louis J.
Institution: Louisiana State University - Baton Rouge
EPA Project Officer: Manty, Dale
Project Period: January 1, 1994 through January 1, 1998
Project Amount: Refer to main center abstract for funding details.
RFA: Hazardous Substance Research Centers - HSRC (1989)
Research Category: Hazardous Substance Research Centers

Description:

Objective:

The main focus of this research is to obtain experimental data on the emission of volatile organic chemicals and metals from contaminated sediments in order to test and validate existing theoretical models. The three major objectives are:

1) To develop and test theoretical models that account for the various parameters that effect air emissions from contaminated dredged material;
2) To measure the toxic chemical flux to air from contaminated mud flats sediment and dredged material using an emission flux chamber;
3) To study the effects of cyclic wet-dry sediment conditions, cyclic flat and cracked surface conditions, cyclic temperature and cyclic humidity on toxic air emissions.

Approach:

The core experiments in this work were conducted in an experimental microcosm, or flux chamber. The chamber was constructed of 1 in anodized aluminum blocks, 30 cm long by 9 cm wide to which a sediment chamber measuring 10 cm long, 3 cm wide and 2 cm deep is attached. An air gap of about 0.2 cm is used to pass air of varying relative humidities. The contaminants that may vaporize into this moving air phase arecollected on an adsorbent trap in the effluent. Inoculated or field-contaminated sediment may be placed in the flux chamber and the potential for volatilization of contaminants measured. The observed vaporization rates were compared to models of the process.

Publications and Presentations:

Publications have been submitted on this subproject: View all 23 publications for this subproject | View all 427 publications for this center

Journal Articles:

Journal Articles have been submitted on this subproject: View all 11 journal articles for this subproject | View all 114 journal articles for this center

Supplemental Keywords:

volatile organic compounds, contaminant flux, and volatilization. , Ecosystem Protection/Environmental Exposure & Risk, Air, Scientific Discipline, Waste, RFA, Chemical Engineering, Analytical Chemistry, air toxics, Hazardous Waste, Environmental Engineering, Environmental Chemistry, Contaminated Sediments, Hazardous, Monitoring/Modeling, Ecology and Ecosystems, risk assessment, Volatile Organic Compounds (VOCs), vaporization, trace metals, contaminated sediment, airborne metals, environmental technology, air qialty model, air pollution, hazardous waste management, contaminated soil, hazardous waste treatment, sediment treatment, volatile air toxics

Progress and Final Reports:
Final Report

Main Center Abstract and Reports:
R825513 HSRC (1989) - South and Southwest HSRC

Subprojects under this Center: (EPA does not fund or establish subprojects; EPA awards and manages the overall grant for this center).
R825513C001 Sediment Resuspension and Contaminant Transport in an Estuary.
R825513C002 Contaminant Transport Across Cohesive Sediment Interfaces.
R825513C003 Mobilization and Fate of Inorganic Contaminant due to Resuspension of Cohesive Sediment.
R825513C004 Source Identification, Transformation, and Transport Processes of N-, O- and S- Containing Organic Chemicals in Wetland and Upland Sediments.
R825513C005 Mobility and Transport of Radium from Sediment and Waste Pits.
R825513C006 Anaerobic Biodegradation of 2,4,6-Trinitrotoluene and Other Nitroaromatic Compounds by Clostridium Acetobutylicum.
R825513C007 Investigation on the Fate and Biotransformation of Hexachlorobutadiene and Chlorobenzenes in a Sediment-Water Estuarine System
R825513C008 An Investigation of Chemical Transport from Contaminated Sediments through Porous Containment Structures
R825513C009 Evaluation of Placement and Effectiveness of Sediment Caps
R825513C010 Coupled Biological and Physicochemical Bed-Sediment Processes
R825513C011 Pollutant Fluxes to Aquatic Systems via Coupled Biological and Physicochemical Bed-Sediment Processes
R825513C012 Controls on Metals Partitioning in Contaminated Sediments
R825513C013 Phytoremediation of TNT Contaminated Soil and Groundwaters
R825513C014 Sediment-Based Remediation of Hazardous Substances at a Contaminated Military Base
R825513C015 Effect of Natural Dynamic Changes on Pollutant-Sediment Interaction
R825513C016 Desorption of Nonpolar Organic Pollutants from Historically Contaminated Sediments and Dredged Materials
R825513C017 Modeling Air Emissions of Organic Compounds from Contaminated Sediments and Dredged Materials title change in last year to "Long-term Release of Pollutants from Contaminated Sediment Dredged Material"
R825513C018 Development of an Integrated Optic Interferometer for In-Situ Monitoring of Volatile Hydrocarbons
R825513C019 Bioremediation of Contaminated Sediments and Dredged Material
R825513C020 Bioremediation of Sediments Contaminated with Polyaromatic Hydrocarbons
R825513C021 Role of Particles in Mobilizing Hazardous Chemicals in Urban Runoff
R825513C022 Particle Transport and Deposit Morphology at the Sediment/Water Interface
R825513C023 Uptake of Metal Ions from Aqueous Solutions by Sediments
R825513C024 Bioavailability of Desorption Resistant Hydrocarbons in Sediment-Water Systems.
R825513C025 Interactive Roles of Microbial and Spartina Populations in Mercury Methylation Processes in Bioremediation of Contaminated Sediments in Salt-Marsh Systems
R825513C026 Evaluation of Physical-Chemical Methods for Rapid Assessment of the Bioavailability of Moderately Polar Compounds in Sediments
R825513C027 Freshwater Bioturbators in Riverine Sediments as Enhancers of Contaminant Release
R825513C028 Characterization of Laguna Madre Contaminated Sediments.
R825513C029 The Role of Competitive Adsorption of Suspended Sediments in Determining Partitioning and Colloidal Stability.
R825513C030 Remediation of TNT-Contaminated Soil by Cyanobacterial Mat.
R825513C031 Experimental and Detailed Mathematical Modeling of Diffusion of Contaminants in Fluids
R825513C033 Application of Biotechnology in Bioremediation of Contaminated Sediments
R825513C034 Characterization of PAH's Degrading Bacteria in Coastal Sediments
R825513C035 Dynamic Aspects of Metal Speciation in the Miami River Sediments in Relation to Particle Size Distribution of Chemical Heterogeneity

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Modeling Air Emissions of Organic Compounds from Contaminated Sediments and Dredged Materials title change in last year to "Long-term Release of Pollutants from Contaminated Sediment Dredged Material"

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