In-Process Recycling of Acetic Acid From Dilute Aqueous Waste Streams
EPA Contract Number: 68D30111Title: In-Process Recycling of Acetic Acid From Dilute Aqueous Waste Streams
Investigators: Baker, Richard W.
Small Business: Membrane Technology and Research Inc.
EPA Contact: Manager, SBIR Program
Phase: I
Project Period: September 1, 1993 through March 1, 1994
Project Amount: $50,000
RFA: Small Business Innovation Research (SBIR) - Phase I (1992)
Research Category: Pollution Prevention/Sustainable Development , SBIR - Pollution Prevention
Description:
Dilute acetic acid wastewater streams are produced in large quantities by the synthetic organic chemical industry, for example, in the synthesis of terephthalic acid, the precursor of polyethylene terephthalate. Recovery of acetic acid from these wastestreams for in-process recycling of the acid would reduce waste and save valuable resources. This proposal describes the development of a process that combines selective dialysis followed by bipolar-membrane electrolysis to recover and concentrate this acid. Although the program focuses on acetic acid recovery, the technology could be applied to recovery and recycling of other weak acids such as acrylic acid, lactic acid, and phenols. Supplemental Keywords:Toxics, Water, Sustainable Industry/Business, Scientific Discipline, Waste, Technology for Sustainable Environment, Wastewater, Engineering, Chemistry, & Physics, Chemistry, Environmental Engineering, cleaner production/pollution prevention, Contaminant Candidate List, Hazardous, New/Innovative technologies, National Recommended Water Quality, 33/50, membrane technology, waste reduction, membrane processes, recovery, membrane-based, aqueous waste stream, in-process recycling, dialysis, aqueous waste, electrochemical, recycling, waste streams, emission control technologies, bipolar-membrane electrolysis, Phenol, phenolic compounds, electrochemical techniques, acetic acid, electrochemcial treatment, pollution prevention, electrochemical technology