U.S. Geological Survey Toxic Substances Hydrology Program--Proceedings
of the Technical Meeting, Colorado Springs, Colorado, September 20-24, 1993,
Water-Resources Investigations Report 94-4015
Effects of Farming Systems on Ground-Water Quality at the Princeton,
Minnesota, Management Systems Evaluation Area, 1991
by
Matthew K. Landon (U.S. Geological Survey, Mounds View, Minn.),
Geoffrey N. Delin (U.S. Geological Survey, Mounds View, Minn.), John A.
Lamb (University of Minnesota, Department of Soil Science, St. Paul,
Minn.), Robert H. Dowdy (U.S. Department of Agriculture, Agricultural Research
Service, St. Paul, Minn.), and James L. Anderson (University of Minnesota,
Department of Soil Science, St. Paul, Minn.)
Abstract
The 65-hectare Management Systems Evaluation Area (MSEA) near Princeton,
Minnesota is one of five primary MSEA's in the Midwest Cornbelt. The Princeton
MSEA program is a cooperative research effort among the U.S. Department
of Agriculture-Agricultural Research Service, the University of Minnesota
Soil Science Department, and the U.S. Geological Survey. The primary program
objective is to evaluate the effects of ridge-tillage practices in corn
and soybean farming systems on ground-water quality in a sand-plain setting.
A sweet-corn and potato farming system is also being evaluated. Analyses
of samples collected at the beginning of the study during April 1991 indicated
that some contamination of ground water with nitrate nitrogen (nitrate-N),
atrazine, and atrazine metabolizes had already occurred before implementation
of the MSEA farming systems.
Chloride in potash fertilizers applied to the MSEA cropped areas in April
1991 was used as a tracer for ground water affected by the MSEA farming
systems. Chloride reached ground water beneath all of the cropped areas.
Analyses of ground-water samples collected during June, August, and December
1991 and during April 1992 indicated that concentrations of chloride in
the upper meter of the saturated zone beneath and downgradient of the cropped
areas were 20 to 50 mg/L (milligrams per liter) compared with background
concentrations of 2 to 19 mg/L.
Because the nitrogen and potash fertilizer application rates on the potato-cropped
area were 1.4 and 4.5 times greater, respectively, than on the other cropped
areas, nitrate-N and chloride concentrations were greatest beneath the potato-cropped
area. Nitrate-N concentrations in the upper meter of the saturated zone
beneath the potato-cropped area (22-47 mg/L) were greater than concentrations
measured upgradient (6-18 mg/L) from the cropped area. Nitrate-N concentrations
were similar upgradient, beneath, and downgradient of the other cropped
areas. Thus, additions of nitrate-N as a result of MSEA activity were difficult
to distinguish from background concentrations. Concentrations of nitrate-N
in the saturated zone across the entire MSEA typically decreased from 15
to 25 mg/L near the water table to 5 to 10 mg/L two meters below the water
table.
Atrazine and atrazine metabolites de-ethylatrazine (DEA) and de-isopropylatrazine
(DIA) were detected in 75, 97, and 76 percent, respectively, of the 124
wells sampled at the Princeton MSEA during the four sampling periods from
June 1991 through April 1992. The concentrations of these compounds in the
saturated zone varied temporally. Atrazine was detected in 51 percent of
the 315 ground-water samples collected in concentrations ranging from less
than 0.01 µg/L (micrograms per liter) to 0.54 µg/L. The median
concentration of atrazine was the detection limit of 0.01 µg/L. DEA
was detected in 74 percent of the samples at concentrations ranging from
less than 0.03 µg/L to 1.00 µg/L. The median concentration of
DEA was 0.08 µg/L. DIA was detected in 10 percent of the samples in
concentrations rangingfrom less than 0.06 µg/L to 0.66 µg/L.
The median concentration of DIA was less than the detection limit of 0.06
µg/L. Alachlor was detected in 2 percent of the samples. Concentrations
of DEA in April 1992 increased with depth from less than 0.06 µg/L
near the water table to 0.08 to 0.30 µg/L between 1 and 2 m below
the water table. This trend with depth was not noticeable prior to April
1992 and could indicate that water recharging the aquifer beneath the cropped
areas during 1991 had lower DEA concentrations than older ground water.
Because some of the applied fertilizers and herbicides and herbicide
metabolites existed in shallow ground water at the onset of this study,
it is difficult to assess the affects of MSEA farming systems on water quality
without additional data collected over several years. None of the detections
of herbicides or herbicide metabolites can be conclusively linked to the
MSEA farming systems at this time. Because some atrazine and atrazine metabolites
were detected in ground water that was recharged through the MSEA cropped
areas, however, the possibility that some of these chemicals leached from
the MSEA farming systems to ground water cannot be discounted. Use of conservative
tracers like chloride and bromide to delineate annual recharge fronts beneath
the MSEA cropped areas should make it easier to identify the affects of
MSEA farming systems on ground-water quality as older ground water affected
by previous farming practices moves horizontally and vertically away from
the cropped areas.
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