U.S. Geological Survey Toxic Substances Hydrology Program--Proceedings
of the Technical Meeting, Colorado Springs, Colorado, September 20-24, 1993,
Water-Resources Investigations Report 94-4015
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Use of Simulation to Study Field-Scale Solute Transport and
Biodegradation at the Bemidji, Minnesota,Crude-Oil Spill Site
by
H.I. Essaid (U.S. Geological Survey, Menlo Park, CA), M.J. Baedecker
(U.S. Geological Survey, Reston, VA), and I.M. Cozzarelli (U.S. Geological
Survey, Reston, VA)
Abstract
A two-dimensional, multispecies solute-transport model that includes
aerobic and anaerobic degradation processes was developed and applied to
the Bemidji, Minnesota, crude-oil spill site. The model was used as a tool
to study the field-scale solute-transport and degradation processes. The
simulations included the transport of degradable and refractory dissolved
organic carbon, dissolved oxygen, and methane, as well as aerobic and anaerobic
(methanogenic) biodegradation. Despite the considerable uncertainty in the
model parameter estimates, results of simulations reproduced the general
features of the observed ground-water plume. In addition to the kinetics
of the biodegradation processes, important factors that affect the distribution
of the solutes in the field are the recharge influx and the degree of dispersion
and mixing in the ground water system. Recharge influx causes flow lines
in the aquifer to be deflected downward from the water table causing downward
movement of the plume. Biodegradation results in a narrow plume with sharp
gradients at the margins. Spatial variability of hydraulic conductivity
increases the amount of carbon degraded by aerobic and anaerobic processes.
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