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Chemical Sampling Information
Tetranitromethane
 Field Definitions
 Analytical Methods
 Health Guidelines
General Description

NAME: Tetranitromethane

SYNONYM(s): TNM

IMIS: 2395

CAS: 509-14-8

NIOSH: RTECS PB4025000; 48121

DOT: UN1510 Oxidizer; Poison

DESCRIPTION:

Colorless to pale yellow liquid or solid with a pungent odor; causes tears.
MW: 196
BP: 259 F
VP: 8.4 mm
MP: 57 F

INCOM: Hydrocarbons, alkalies, metals

Exposure Limits

OSHA GENERAL INDUSTRY PEL: 1 ppm, 8 mg/m3

OSHA CONSTRUCTION INDUSTRY PEL: 1 ppm, 8 mg/m3 TWA

ACGIH TLV: 0.005 ppm, 0.04 mg/m3 TWA; Appendix A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans)

NIOSH REL: 1 ppm TWA

Health Factors

SYMPTOM(s): Eye, nose, throat irritation; dizziness; headaches; chest pain, dyspnea; methemoglobinuria; cyanosis; skin burns

HEALTH EFFECTS: Irritation-Eye, Nose, Throat, Skin---Marked (HE14) Acute CNS and lung effects (HE4); Cumulative systemic damage (HE3) Methemoglobinemia (HE13)

ORGAN: Respiratory system, eyes, skin, blood, CNS

Monitoring

PRIMARY SAMPLING/ANALYTICAL METHOD (SLC1):



MEDIA: Midget Impinger containing 15 mL Ethyl Acetate
MAX V: 250 Liters   MAX F: 1.0 L/min
ANL 1: Gas Chromatography; GC/NPD
REF: 1 (NIOSH S-224)
SAE: 0.13
CLASS: Fully Validated


Revision Date: 01/15/1999
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