U.S. Geological Survey Toxic Substances Hydrology Program--Proceedings
of the Technical Meeting, Colorado Springs, Colorado, September 20-24, 1993,
Water-Resources Investigations Report 94-4015
Concentrations of Chlorofluorocarbons and Other Gases in Ground
Water at Mirror Lake, New Hampshire
by
Eurybiades Busenberg (U.S. Geological Survey, Mail Stop 432,
Reston, VA) and L. Niel Plummer (U.S. Geological Survey, Mail Stop 432,
Reston, VA)
Abstract
The concentrations of chlorofluorocarbons (CFC's)
were measured in samples of ground water from 51 different
depth intervals in wells completed in the low-permeability
glacial till and fractured crystalline rocks at Mirror
Lake. The CFC concentrations were used to model water-recharge
ages. The ground-water ages generally increased with
depth from land surface and were consistent with the
reconstructed tritium (3H) concentrations. A
6°C water-recharge temperature was obtained from
the nitrogen (N2) to argon (Ar) ratios from the wells completed
in the glacial till. The dissolved N2, Ar, and helium
concentrations generally increased with depth from
land surface. Excess air in ground water ranges from
about 0 to 19 cubic centimeters per liter in some
deep wells. In addition to the excess air, some wells
contain significant amounts of excess N2. Enrichment in the concentrations
of sulfate, calcium, and magnesium were present
in some ground waters with CFC-recharge ages of 1963 to
1973.
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