MTBE, Oxygenates, and Motor Gasoline



Contents


Introduction

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

Unfortunately, because of leaking underground storage tanks or spills and because MTBE is soluble in water and does not biodegrade easily, there have been increasing detections of MTBE in ground waters and reservoirs.

Because of the occurrence of MTBE in water supplies, the EPA formed the Blue Ribbon Panel On Oxygenates in Gasoline. In September 1999, the Panel issued its final report that included the following recommendations on MTBE use:(1)

In December 1999, the California Air Resources Board approved the California Phase 3 gasoline regulation, which prohibits the formulation of gasoline with MTBE after December 31, 2002. Governor Davis has also asked the U.S. EPA to waive the reformulated gasoline oxygen requirement. A decision from the U.S. EPA is pending.

This Short-Term Energy Outlook (March 2000) assumes no change in the current EPA regulations regarding the blending of MTBE into gasoline or the required properties of reformulated gasoline. Because this short-term forecast extends only through December 2001, no impact from the California ban on MTBE is included.

The purpose of this analysis is to identify the issues related to the recommendations of the EPA's Blue Ribbon Panel and how they may impact our forecasts.


Federal gasoline product quality regulations

As required by the Clean Air Act, the U.S. petroleum refining industry has responded to 5 major new Federal rules on motor gasoline product quality in the last 11 years:

Environmental Regulations Affecting the Product Quality of U.S. Motor Gasoline
Phase 1 Summer Volatility (RVP) RegulationJune 1989
Phase 2 Summer Volatility (RVP) RegulationMay 1992
Oxygenated GasolineNovember 1992
Reformulated Gasoline Phase 1December 1994
Reformulated Gasoline Phase 2January 2000

Oxygenates were first required in the wintertime oxygenated gasoline program to reduce exhaust emissions of carbon monoxide (CO) in 39 areas of the country. The oxygenated gasoline program requires oxygen at a minimum level of 2.7 weight percent (equivalent to 15.0 volume percent MTBE or 7.4 volume percent fuel ethanol).

The reformulated gasoline (RFG) program requires reductions in automobile emissions of ozone-forming volatile organic compounds during the summer high-ozone season, and of toxic air pollutants and nitrogen oxides during the entire year in certain areas of the United States. Reformulated gasoline requires a minimum 2.1 percent oxygen by weight when averaging, which corresponds to approximately 11.7 volume percent MTBE or 5.8 volume percent ethanol. While the sale of Federal reformulated gasoline was mandated for only nine areas in the nation with the most severe ozone pollution, other areas are allowed to voluntarily join the Federal RFG program.


What are oxygenates?

Oxygenates are hydrocarbons that contain one or more oxygen atoms. The primary oxygenates are alcohols and ethers, including: fuel ethanol, methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), and tertiary amyl methyl ether (TAME).

The 1977 Clean Air Act amendments set requirements for "substantially similar gasoline," which requires that oxygenates be approved by the U.S. EPA before they are allowed to be used in gasoline. In 1981 the EPA allowed the blending of MTBE up to 11 volume percent, and extended the limit to 15 volume percent in 1988.

Oxygenates are added to motor vehicle fuels to make them burn more cleanly, thereby reducing toxic tailpipe pollution, particularly carbon monoxide. Oxygenates are favored not only for their vehicle emission benefits but also their blending properties in motor gasoline (e.g., octane).

Table 1. Typical Properties of Oxygenates

  Ethanol MTBE ETBE TAME

Chemical formula   CH3CH2OH     CH3OC(CH3)3     CH3CH2OC(CH3)3     (CH)3CCH2OCH3  
Oxygen content, percent by weight 34.73 18.15 15.66 15.66
Octane, (R+M)/2 115 110 111 105
Blending vapor pressure, RVP 18 8 4 1.5

Source: National Petroleum Council, U.S. Petroleum Refining: Meeting Requirements for Cleaner Fuels and Refineries (Washington, DC, August 1993) Appendix L.


Who gets gasoline with oxygenates?

Reformulated gasoline makes up about one-third of all gasoline sold in the United States. Oxygenated gasoline makes up about 5 percent of the gasoline sold during the winter months (November through February) and averages about 1.3 percent over the full year.(2)

Figure 1. Reformulated and Oxygenated Gasoline Demand by PADD, 1997
(thousands of barrels per calendar day)

Refer to Table 2 for data

Table 2. Reformulated and Oxygenated Gasoline Demand by PADD, 1997
(thousands of barrels per calendar day)

PADD Region Reformulated
Gasoline
Oxygenated-Reformulated
Gasoline
Oxygenated
Gasoline

   PADD 1 - East Coast 1,052   138      0
   PADD 2 - Midwest   282      0   105
   PADD 3 - Gulf Coast   270      0    19
   PADD 4 - Rocky Mountain      0      0    36
   PADD 5 - West Coast   915    13    73
   Subtotal U.S. 2,522   151   233

Sources: Control area gasoline demand calculated from control area population as share of State population and 1997 State gasoline demand from Federal Highway Administration, "Monthly Gasoline Reported by States," Highway Statistics 1997, FHWA-PL-98-020 (Washington, DC, Nov. 1, 1998), Table MF-33GA.

For additional information refer to:

Environmental Protection Agency
Oxygenated gasoline program areas
Reformulated gasoline program areas

Energy Information Administration
Oxygenated gasoline program areas
Reformulated gasoline program areas
Oxygenated and Reformulated Gasoline Sales by State:
      Petroleum Marketing Monthly Table 48
      Petroleum Marketing Annual Table 48


Which areas get MTBE?

While EIA reports monthly data on production, imports, and stocks of individual oxygenates, there is no comparable data on the disposition of oxygenates. However, an oxygenate demand balance can be derived from EPA estimates of the oxygenate content in reformulated and oxygenated gasoline by control area. MTBE is the dominant blendstock in reformulated gasoline, and ethanol is generally the oxygenate of choice in oxygenated gasoline. Almost all MTBE supply is used for reformulated and oxygenated gasoline blending, while only about one-half of the total ethanol supply is. Demand for ethanol in gasohol blending and MTBE as a motor gasoline octane blendstock make up the balance of the oxygenate demands.

[Click here for estimated oxygenate demands by control area in an Excel .XLS file]

Table 3. Oxygenate Demand in Reformulated and Oxygenated Gasoline Control Areas, 1997
(thousands of barrels per calendar day)

   Region Estimated Oxygenate Volume
in Control Area Gasoline

MTBE ETBE
  or TAME  
Ethanol

Reformulated Gasoline
   PADD 1 - East Coast 110.8 8.7 0.7
   PADD 2 - Midwest   4.2 0.0 22.4
   PADD 3 - Gulf Coast  25.8 3.0 1.0
   PADD 4 - Rocky Mountain   0.0 0.0 0.0
   PADD 5 - West Coast  97.2 3.3 1.0
   Subtotal U.S. 238.1 15.0 24.2
 
Oxygenated-Reformulated Gasoline
   PADD 1 - East Coast  17.8 0.0 1.6
   PADD 5 - West Coast   0.1 0.0 1.2
   Subtotal U.S.  17.9 0.0 2.8
 
Oxygenated Gasoline
   PADD 1 - East Coast   0.0 0.0 0.0
   PADD 2 - Midwest   0.0 0.0 9.0
   PADD 3 - Gulf Coast   0.0 0.0 1.7
   PADD 4 - Rocky Mountain   0.3 1.1 2.5
   PADD 5 - West Coast   0.5 0.0 5.1
   Subtotal U.S.   0.8 1.1 18.3
 
Average 1997 Oxygenate Demand for RFG and Oxygenated Gasoline Blending 257 16 45
 
Imputed Oxygenate Demand for Conventional Gasoline (e.g., octane and gasohol)  12 n.a. 37
 
Total 1997 Oxygenate Supply 269 n.a. 82

n.a. - not available
Notes: Total oxygenate supply includes domestic production, net imports, and stock change. Imports of RFG (161,000 barrels per day) assumed to contain 11.2 percent MTBE by volume.

Sources: Oxygenate content in RFG control area gasoline: Environmental Protection Agency, 1997 RFG Surveys Oxygenate Information. Oxygenate market shares in oxygenated gasoline control areas: Environmental Protection Agency, State Winter Oxygenated Fuel Programs, February 1, 1999. Control area gasoline demand calculated from control area population as share of State population and 1997 State gasoline demand from Federal Highway Administration, "Monthly Gasoline Reported by States," Highway Statistics 1997, FHWA-PL-98-020 (Washington, DC, Nov. 1, 998), Table MF-33GA. Oxygenate supply: Energy Information Administration, Petroleum Supply Annual 1997, Volume 1, DOE/EIA-0340(97)/1 (Washington, DC, June 1998), Tables 3, 20, 27, 30; and EIA-819M Monthly Oxygenate Telephone Report.


How much has been invested in MTBE production capacity?

Although we do not have an estimate of the total investment in MTBE production plants over the last 20 years, we can estimate the current replacement cost of existing MTBE capacity. If only MTBE use is banned, capacity can be converted to the production of ETBE. If all ether use is banned, the conversion of existing MTBE production equipment to alternative uses may be very limited.

There are three types of MTBE production plants:

The total cost of replacing the existing MTBE production capacity would range from about $2.6 billion to $3.8 billion.


What does new Ethanol capacity cost?

There are two types of ethanol production processes: wet milling and dry milling. The capital cost for building a new wet mill plant is about $2.00 per annual gallon, and $1.50 per annual gallon for a dry mill plant.(3) If all ethers were banned and the reformulated gasoline minimum oxygen requirement maintained, new ethanol plant capacity would be required to replace the ethers. If we assume that all ethanol would go to oxygenated or reformulated gasoline and none into conventional gasohol, an investment of about $2 billion in new ethanol plant capacity would be required.

Table 4. Estimated New Ethanol Capacity Required based on 1997 volumes
(barrels per calendar day)

Ethers (MTBE, ETBE, and TAME) blended into oxygenated and reformulated gasoline 285,000
Ethanol required to substitute for ethers
(at contained oxygen equivalency of 1/2 gal ethanol = 1 gal ether)  
142,000
Less ethanol blended into gasohol available for reformulated gasoline market - 37,000
Less existing unused ethanol production capacity - 15,000
Net new ethanol capacity required 91,000

Notes: For total ether volume and ethanol blended into gasohol (conventional gasoline) refer to Table 3. Existing unused capacity based on 1999 average ethanol production of 95,000 barrels per day with production capacity of about 110,000 barrels per day.(4)

Cost of building new ethanol (dry milling) capacity:

   $ 1.50 per annual gallon (e.g., 10 million gallon per year plant = $15 million)
= $63 per annual barrel (e.g., 238,000 barrel per year plant = $15 million)
= $22,995 per barrel per calendar day (e.g., 652 barrel per calendar day plant = $15 million)
x 91,000 barrels per calendar day
= $2.1 billion

There would also be additional capital costs for the distribution infrastructure to transport and blend ethanol into gasoline. In just California the capital cost for ethanol distribution infrastructure was estimated to total $60 million.(3)

Other considerations:


What would an MTBE ban cost?

The primary policy options to reduce the use of MTBE in gasoline blending are the elimination of the minimum oxygen requirement in reformulated gasoline and a ban on the use of MTBE and possibly other ethers. Cost estimates have focused on the following four policy combinations, in order of increasing expense:

The cost estimates cover either California only or the entire U.S. The wider the MTBE ban the higher the cost should be. The estimated costs are typically average rather than marginal costs. Costs of an MTBE ban will be higher for some refiners and regions and lower for others. It should also be noted that the published cost estimates do not reflect the cost of operating under the EPA's new sulfur reduction requirements (Tier 2 gasoline) that begin in 2004.

The price of ethanol in most studies is assumed to be the market price, which includes the 54 cents per gallon Federal excise tax exemption. The addition of 100,000 barrels per day of ethanol to the gasoline pool would reduce Federal excise tax revenues by about $800 million per year.(5)


On-line information resources

Energy Information Administration, U.S. Dept. of Energy

Environmental Protection Agency

International Trade Commission

House Science Subcommittee on Energy and Environment

California Energy Commission

Renewable Fuels Association


Endnotes

1. EPA Blue Ribbon Panel, Achieving Clean Air and Clean Water: The Report of the Blue Ribbon Panel on Oxygenates in Gasoline (Washington, DC, September 15, 1999).

2. The oxygenated gasoline market share has been higher in previous years but because of improved air quality a number of areas no longer require oxygenated gasoline.

3. California Energy Commission, Supply and Cost Alternatives to MTBE in Gasoline, P300-98-013 (Sacramento, CA, February 1999). Wet mill plant capital cost from California Energy Commission. Dry mill plant capital cost from Renewable Fuels Association. The $1.50 per annual gallon dry mill plant cost estimated by the Renewable Fuels Association is lower than the $2.50 per annual gallon cost reported by the California Energy Commission.

4. Ethanol production from Energy Information Administration, EIA-819M Monthly Oxygenate Telephone Report. Capacity from Renewable Fuels Association, The Ethanol Industry Outlook - 1999 and Beyond (Washington, DC, February 1999) and California Energy Commission, Staff Report: Supply and Cost Alternatives to MTBE in Gasoline, Appendix B, P300-98-013 (Sacramento, CA, February 1999).

5. The Federal excise tax exemption is currently $0.54 per gallon and it is scheduled to drop to $0.53 on January 1, 2001, $0.52 on January 1, 2003, $0.51 on January 1, 2005., and expire on December 31, 2006. The loss of excise tax revenue may be offset by reduced farm program spending on marketing assistance loans. The U.S. Department of Agriculture estimates that a complete phaseout of MTBE would increase the average corn price by about $0.14 per bushel. Where loan deficiency payments are being made, each $0.10 per bushel increase in corn prices could lower farm program payments by about $1 billion per year. However, the USDA also reports that under the FY2000 President's Budget baseline, farm crop prices are expected to strengthen from current levels, which results in increased ethanol use having little or no impact on the forecast cost of farm price and income support programs. U.S. Department of Agriculture, Economic Analysis of Replacing MTBE with Ethanol in the United States (Washington, DC).

6. Assumes that refiners continue to use the "averaging" option. Cost estimates for operating under the "flat limit" are generally lower. But the risk of producing off-spec material under the flat limit and reprocessing costs are not included and may be significant. California Energy Commission, Supply and Cost Alternatives to MTBE in Gasoline, P300-98-013 (Sacramento, CA, February 1999).

7. Energy Information Administration, Annual Energy Outlook 2000, Appendix F (Washington, DC, December 17, 1999).

8. Includes 3 cent per gallon Federal excise tax credit for 6 volume percent ethanol. Robert E. Cunningham, Turner, Mason & Company, Costs of Potential Ban of MTBE in Gasolines, presented to EPA Blue Ribbon Panel to Review the Use of Oxygenates in Gasoline, March 2, 1999.


Summary of Revisions to this Analysis

Originally published to Internet: February 7, 2000

Revisions March 6, 2000:


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File last modified: March 6, 2000.

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