Mark R. Antonio

Mark R. Antonio (PhD, Michigan State University, 1983) is an inorganic chemist. His activities are centered on materials syntheses–including actinide/lanthanide-element reactions and polyoxometalates–and the characterization of solids and solutions of fundamental importance in separations science and heavy element chemistry, through use of synchrotron radiation research (XAS and SAXS), electroanalytical chemistry, molecular spectroscopy, and in situ techniques.

Publications

Europium(III) reduction and speciation within a Wells-Dawson heteropolytungstate
J. Jing; B. P. Burton-Pye, L. C. Francesconi, M. R. Antonio
Inorg. Chem., in press (2008)

Tetraalkylphosphonium polyoxometalates as novel ionic liquids
M. L. Dietz, P. G. Rickert, M. R. Antonio, M. A. Firestone, J. F. Wishart, and T. Szreder
Proc. 18^th International Solvent Extraction Conference, Tucson, AZ, in press (2008)

Evidence of trivalent europium incorporated in anatase TiO₂ nanocrystals with multiple sites
W. Luo, R. Li, G. Liu, M. R. Antonio, and X. Chen
J. Phys. Chem. C, in press (2008)

Aggregation in solvent extraction systems containing a malonamide, a dialkylphosphoric acid, and their mixtures
M. R. Antonio, R. Chiarizia, B. Gannaz, L. Berthon, N. Zorz, C. Hill, and G. Cote
Sep. Sci. Technol., in press (2008)

A comparison of neptunyl(V) and neptunyl(VI) solution coordination: The stability of cation-cation interactions
S. Skanthakumar, M. R. Antonio, and L. Soderholm
Inorg. Chem. 47(11), 4591-4595 (2008)

Optical spectroscopy of Eu³⁺ doped ZnO nanocrystals
Y. Liu, W. Luo, R. Li, G. Liu, M. R. Antonio, and X. Chen
J. Phys. Chem. C 112(3), 686-694 (2008)

Tetraalkylphosphonium polyoxometalate ionic liquids: Novel, organic-inorganic hybrid materials
P. G. Rickert, M. R. Antonio, M. A. Firestone, K.-A. Kubatko, T. Szreder, J. F. Wishart, and M. L. Dietz
J. Phys. Chem. B 111(18), 4685-4692 (2007)

The curium aqua ion
S. Skanthakumar, M. R. Antonio, R. E. Wilson, and L. Soderholm
Inorg. Chem. 46(9), 3485-3491 (2007)

Extraction of lanthanides(III) and Am(III) by mixtures of malonamide and dialkylphosphoric acid
B. Gannaz, R. Chiarizia, M. R. Antonio, C. Hill, and G. Cote
Solvent Extr. Ion Exch. 25(3), 313-337 (2007)

Tetraalkylphosphonium polyoxometalates: Electroactive, “task-specific” ionic liquids
P. G. Rickert, M. R. Antonio, M. A. Firestone, K.-A. Kubatko, T. Szreder, J. F. Wishart, and M. L. Dietz
Dalton Trans. 529-531 (2007)

Structural study of trivalent lanthanide and actinide complexes formed upon solvent extraction (Cover Article)
B. Gannaz, M. R. Antonio, R. Chiarizia, C. Hill, and G. Cote
Dalton Trans. 4553-4562 (2006)

X-ray absorption spectroscopy of the actinides
M. R. Antonio and L. Soderholm
In The Chemistry of the Actinide and Transactinide Elements, 3rd Ed., L. R. Morss, N. Edelstein, J. Fuger, and J. J. Katz, Eds., Springer, 2006, Vol. 5, Chapter 28, pp. 3086-3198

Presence and persistence of uranyl peroxide nanoclusters in contact with geological media
K.-A. Kubatko, K. M. Gunderson, M. Antonio, P. C. Burns, L. Soderholm
Mater. Res. Soc. Symp. Proc. 893, 387-392 (2006)

Actinides 2005—Basic Science, Applications and Technology
J. L Sarrao, A. J. Schwartz, M. R. Antonio, P. C. Burns, R. G. Haire, and H. Nitsche, Eds.
Materials Research Society: Warrendale, PA, Vol. 893 (2006) 439 pp.

Actinyl peroxide nanospheres (Cover Article)
P. C. Burns, K.-A. H. Kubatko, G. Sigmon, B. J. Fryer, J. Gagnon, M. R. Antonio, and L. Soderholm
Angew. Chem., Int. Ed. 44 (14), 2135-2139 (2005)

Redox chemistry of the Keggin heteropolyoxotungstate anion in ionic liquids
M-H. Chiang, J. A. Dzielawa, M. L. Dietz, and M. R. Antonio
J. Electroanalytical Chem. 567 (1), 77-84 (2004)

Energetics of the Preyssler anion’s molecular orbitals: Quantifying the effect of the encapsulated-cation’s charge
M.-H. Chiang, M. R. Antonio, and L. Soderholm
Dalton Trans. 3562-3567 (2004)

A unique coordination environment for an ion: EXAFS studies and bond valence model approach of the encapsulated cation in the Preyssler anion
M-H. Chiang, M. R. Antonio, C. W. Williams, and L. Soderholm
Dalton Trans. 5, 801-806 (2004)

In situ actinide X-ray absorption spectroelectrochemistry
M. R. Antonio, M.-H. Chiang, C. W. Williams, and L. Soderholm
Mater. Res. Soc. Symp. Proc. 802, 157-168 (2004)

Redox chemistry of actinide ions in Wells-Dawson heteropolyoxoanion complexes (Cover Article)
M-H. Chiang, L. Soderholm, and M. R. Antonio
Eur. J. Inorg. Chem. (16), 2929-2936 (2003)

Coordination of actinide ions in Wells-Dawson heteropolyoxoanion complexes
M-H. Chiang, C. W. Williams, L. Soderholm, and M. R. Antonio
Eur. J. Inorg. Chem. 14, 2663-2669 (2003)

Berkelium redox speciation
M. R. Antonio, C. W. Williams, and L. Soderholm
Radiochim. Acta 90, 851-856 (2002)

In situ Ru L_II and L_III-edge X-ray absorption near edge structure of electrodeposited ruthenium dioxide films
I. C. Stefan, Y. Mo, M. R. Antonio, D. A. Scherson
J. Phys. Chem. B 106 (48), 12373-12375 (2002)

In situ sulfur K-edge X-ray absorption near edge structure of an embedded pyrite particle electrode in a non-aqueous Li⁺-based electrolyte solution
D. A. Totir, M. R. Antonio, P. Schilling, R. Tittsworth, D. A. Scherson
Electrochim. Acta 47 (19), 3195-3200 (2002)

Correlated electrons in the Eu-exchanged Preyssler anion [EuP₅W₃₀O₁₁₀]^n-
L. Soderholm, M. R. Antonio, S. Skanthakumar, and C. W. Williams
J. Am. Chem. Soc. 124 (25), 7290-7291 (2002)

Coordination of rare-earth elements in complexes with monovacant Wells-Dawson polyoxoanions
Q-H. Luo, R. C. Howell, M. Dankova, J. Bartis, C. W. Williams, W. DeW. Horrocks, Jr., V. G. Young, Jr., A. L. Rheingold, L. C. Francesconi, and M. R. Antonio
Inorg. Chem. 40, 1894-1901 (2001)

The coordination geometry of Np(VII) in alkaline solution
C. W. Williams, J.-P. Blaudeau, J. C. Sullivan, M. R. Antonio, B. Bursten, and L. Soderholm
J. Am. Chem. Soc. 123, 4346-4347 (2001)

Neptunium redox speciation
M. R. Antonio, L. Soderholm, C. W. Williams, J. P. Blaudeau, and B. E. Bursten
Radiochim. Acta 89 (1), 17-25 (2001)

Probing redox reactions at a synchrotron: The coordination geometry of Np(VII)
C. W. Williams, J. C. Sullivan, M. R. Antonio, and L. Soderholm
APS Forefront 1, 152-154 (2001)

Formation of UO₂(BO₃)₄ clusters in B₂O₃ blass due to charge transfer and vibronic effects
G. K. Liu, V. S. Vikhnin, H. Z. Zhuang, K. S. Hong, J. V. Beitz,
M. R. Antonio, L. Soderholm, and C. W. Williams
J. Luminescence 94-95, 677-681 (2001)

Characterization of materials: XEOL/XAS
L. Soderholm, G. K. Liu, M. R. Antonio, and M. F. Reid
The Encyclopedia of Materials: Science and Technology, Pergamon Press, Amsterdam, pp. 1140-1142 (2001)

The formation and stability of [EuP₅W₃₀O₁₁₀]^12- and [AmP₅W₃₀O₁₁₀]^12-
C. W. Williams, M. R. Antonio, and L. Soderholm
J. Alloys Compd. 303-304, 509-513 (2000)

In situ Co K-edge X-ray absorption fine structure of cobalt hydroxide film electrodes in alkaline solutions
D. Totir, Y. Mo, S. Kim, M. R. Antonio, and D. A. Scherson
J. Electrochem. Soc. 147 (12), 4594-4597 (2000)

Utilization of principal component analysis on plutonium EXAFS data from the advanced photon source
J. Terry, R. K. Schulze, T. G. Zocco, J. D. Farr, J. Archuleta, M. Ramos, R. Martinez, B. Martinez, R. Pereyra, J. Lashley, S. Wasserman, M. Antonio, S. Skanthakumar, and L. Soderholm
AIP Conf. Proc. 532 (Plutonium Futures--The Science), 364-366 (2000)

The influence of Desulfovibrio desulfuricans on neptunium chemistry
L. Soderholm, C. W. Williams, M. R. Antonio, M. L. Tischler, and M. Markos
Mater. Res. Soc. Symp. Proc. 590 (Applications of Synchrotron Radiation Techniques to Materials Science V), 27-32 (2000)

In-situ Ru K-edge x-ray absorption fine structure studies of electroprecipitated ruthenium dioxide films with relevance to supercapacitor applications
Y. Mo, M. R. Antonio, and D. A. Scherson
J. Phys. Chem. B 104 (42), 9777-9779 (2000)

Studies of local structure of Cm³⁺ in borosilicate glass using laser and x-ray spectroscopic methods and computational modeling
G. K. Liu, V. V. Zhorin, M. R. Antonio, S. T. Li, C. W. Williams, and L. Soderholm
J. Chem. Phys. 112 (3), 1489-1496 (2000)

Iron chemistry in petroleum production
M. R. Antonio, G. B. Karet, and J. P. Guzowski, Jr.
Fuel 79 (1), 37-45 (2000)

Extracellular iron-sulfur precipitates from growth of Desulfovibrio desulfuricans
M. R. Antonio, M. L. Tischler, and D. Witzcak
Mater. Res. Soc. Symp. Proc. 590 (Applications of Synchrotron Radiation Techniques to Materials Science V), 33-38 (2000)

XANES Spectroelectrochemistry: A new method for determining formal potentials
L. Soderholm, M. R. Antonio, C. Williams, and S. R. Wasserman
Anal. Chem. 71 (20), 4622-4628 (1999)

Redox behavior of cerium in heteropolyoxotungstate complexes
M. R. Antonio, L. Soderholm, C. W. Williams, N. Ullah, and L. C. Francesconi
J. Chem. Soc., Dalton Trans. (21), 3825-3830 (1999)

Tetravalent uranium in calcite
N. C. Sturchio, M. R. Antonio, L. Soderholm, S. R. Sutton, and J. C. Brannon
Science (Washington, D. C.) 281 (5379), 971-973 (1998)

X-ray excited optical luminescence (XEOL) detection of x-ray absorption fine structure (XAFS)
L. Soderholm, G. K. Liu, M. R. Antonio, and F. W. Lytle
J. Chem. Phys. 109 (16), 6745-6752 (1998)

Synthesis and characterization of actinide-exchanged Preyssler heteropolyanions [AnP₅W₃₀O₁₁₀]^n- (An = Th, Am, Cm)
M. R. Antonio, C. W. Williams, and L. Soderholm
J. Alloys Compd. 271-273, 846-849 (1998)

Coordination and valence of europium in [Eu(a-2-As₂W₁₇O₆₁)₂]^17- and [Eu(W₅O₁₈)₂]^9-
M. R. Antonio, L. Soderholm, G. Jennings, L. C. Francesconi, M. Dankova, and J. Bartis
J. Alloys Compd. 275-277, 827-830 (1998)

In situ Fe K-Edge x-ray absorption fine structure of a pyrite electrode in a Li/Polyethylene oxide(LiClO₄)/FeS₂ battery environment
D. A. Totir, I. T. Bae, Y. Hu, M. R. Antonio, M. A. Stan, and D. A. Scherson
J. Phys. Chem. B 101 (47), 9751-9756 (1997)

Oxidation state of the unusual rare earth (R = Ce, Pr and Tb) in double-layer high-Tc superconductors
U. Staub, L. Soderholm, S. Skanthakumar, and M. R. Antonio
J. Phys. IV 7 (C2, X-Ray Absorption Fine Structure, Vol. 2), 1077-1079 (1997)

The effect of f-ion valence on superconductivity in the series Pb₂Sr₂RCu₃O₈ (R = Ce, Pr, Tb and Am)
L. Soderholm, S. Skanthakumar, U. Staub, M. R. Antonio, and C. W. Williams
J. Alloys Compd. 250 (1-2), 623-626 (1997)

In situ x-ray absorption fine structure studies of a manganese dioxide electrode in a rechargeable MnO₂/Zn alkaline battery environment
Y. Mo, Y. Hu, I. T. Bae, B. Miller, M. R. Antonio, and D. A. Scherson
J. Electrochem. Soc. 144 (5), 1598-1603 (1997)

In situ x-ray absorption fine structure and optical reflectance studies of electrodeposited nickel hydrous oxide films in alkaline electrolytes
Y. Hu, I. T. Bae, Y. Mo, M. R. Antonio, and D. A. Scherson
Can. J. Chem. 75 (11), 1721-1729 (1997)

EXAFS studies of cesium complexation by dibenzo-crown ethers in tri-n-butyl phosphate
M. R. Antonio, M. L. Dietz, M. P. Jensen, L. Soderholm, and E. P. Horwitz
Inorg. Chim. Acta 255 (1), 13-20 (1997)

Local environments of erbium and lutetium in sodium silicate glasses
M. R. Antonio, L. Soderholm, and A. J. G. Ellison
J. Alloys Compd. 250 (1-2), 536-540 (1997)

Implications of the unusual redox behavior exhibited by the heteropolyanion [EuP₅W₃₀O₁₁₀]^12-
M. R. Antonio and L. Soderholm
J. Alloys Compd. 250 (1-2), 541-543 (1997)

Design of spectroelectrochemical cell for in-situ x-ray absorption fine structure measurements of bulk solution species
M. R. Antonio, L. Soderholm, and I. Song
J. Appl. Electrochem. 27 (7), 784-792 (1997)

The synthesis and characterization of the superconductor-related compound Pb₂Sr₂AmCu₃O₈
L. Soderholm, C. Williams, S. Skanthakumar, M. R. Antonio, and S. Conradson
Z. Phys. B: Condens. Matter 101 (4), 539-545 (1996)

In situ vanadium K-edge and tungsten L_III-edge S-ray absorption fine structure of vanadium-substituted heteropolytungstates immobilized in a high-area carbon electrode in acid aqueous electrolytes
D. E. Clinton, D. A. Tryk, I. T. Bae, F. L. Urbach, M. R. Antonio, and D. A. Scherson
J. Phys. Chem. 100 (47), 18511-18514 (1996)

Comparison of the cation valences and coordinations in Ce₂UO₆ and Ce₂MoO₆
M. R. Antonio, U. Staub, J. S. Xue, and L. Soderholm
Chem. Mater. 8 (11), 2673-2680 (1996)

Redox behavior of europium in the Preyssler heteropolyanion [EuP₅W₃₀O₁₁₀]^12-
M. R. Antonio and L. Soderholm
J. Cluster Sci. 7 (4), 585-591 (1996)

Polymorphs of Ln₂MoO₆: A neutron diffraction investigation of the crystal structures of La₂MoO₆ and Tb₂MoO₆
J. S. Xue, M. R. Antonio, and L. Soderholm
Chem. Mater. 7 (2), 333-40 (1995)

Electrochemical insertion of lithium into pyrite from nonaqueous electrolytes at room temperature: An in situ Fe K-edge x-ray absorption fine structure study
D. A. Tryk, S. Kim, Y. Hu, W. Xing, D. A. Scherson, M. R. Antonio, V. Z. Leger, and G. E. Blomgren
J. Phys. Chem. 99 (11), 3732-5 (1995)

In situ X-ray absorption fine structure measurements of LaNi₅ electrodes in alkaline electrolytes
D. A. Tryk, I. T. Bae, Y. Hu, S. Kim, M. R. Antonio, and D. A. Scherson
J. Electrochem. Soc. 142 (3), 824-8 (1995)

In situ La, Ce, and Nd L-edge X-ray absorption fine structure study of an intermetallic metal hydride electrode in an operating alkaline battery
D. A. Tryk, I. T. Bae, D. Scherson, M. R. Antonio, G. W. Jordan, and E. L. Huston
J. Electrochem. Soc. 142 (5), L76-L78 (1995)

Oxidation state and magnetic properties of Pb₂Sr₂Tb_1-xY_xCu₃O₈ U. Staub, L. Soderholm, S. Skanthakumar, and M. R. Antonio
Phys. Rev. B: Condens. Matter 52 (13), 9736-45 (1995)

In situ total-electron-yield sulfur K-edge XAFS measurements during exposure of copper to an SO₂-containing humid atmosphere
I. Song, B. Rickett, P. Janavicius, J. H. Payer, and M. R. Antonio
Nucl. Instrum. Methods Phys. Res., Sect. A 360 (3), 634-41 (1995)

An iron K-edge XANES study of iron and iron oxides for the cathodic disbonding of fusion bonded epoxy in alkaline aqueous solution
I. Song, M. R. Antonio, and J. H. Payer
J. Electrochem. Soc. 142 (7), 2219-24 (1995)

Coordination and valence of europium in the heteropolyanion [EuP₅W₃₀O₁₁₀]^12-
L. Soderholm, G. K. Liu, J. Muntean, J. Malinsky, and M. R. Antonio
J. Phys. Chem. 99 (23), 9611-16 (1995)

The oxidation state and magnetic behavior of Tb in high-Tc related materials
L. Soderholm, U. Staub, S. Skanthakumar, and M. R. Antonio
Mater. Res. Soc. Symp. Proc. 376 (Neutron Scattering in Materials Science II),
529-34 (1995)

In situ extended X-ray absorption fine structure of an iron porphyrin irreversibly adsorbed on an electrode surface
S. Kim, D. Tryk, I. T. Bae, M. Sandifer, R. Carr, M. R. Antonio, and D. A. Scherson
J. Phys. Chem. 99 (25), 10359-64 (1995)

Synthesis and properties of lanthanide-exchanged Preyssler's heteropolyanions
M. R. Antonio, J. Malinsky, and L. Soderholm
Mater. Res. Soc. Symp. Proc. 368 (Synthesis and Properties of Advanced Catalytic Materials), 223-8 (1995)

The electronic properties of Ce in CeFe₄P₁₂
S. J. Xue, M. R. Antonio, W. T. White, L. Soderholm, and S. M. Kauzlarich
J. Alloys Compd. 207-208, 161-4 (1994)

Tb oxidation state and hybridization in Y_0.9Tb_0.1Ba₂Cu₃O_7-d (d = 0.02, 0.84): a magnetic-susceptibility and x-ray-absorption study
U. Staub, M. R. Antonio, L. Soderholm, M. Guillaume, W. Henggeler, and A. Furrer
Phys. Rev. B: Condens. Matter 50 (10), 7085-91 (1994)

The application of x-ray absorption spectroscopy to the analysis of tarnish products formed in mixed flowing gas environments
B. I. Rickett, I. Song, P. Janavicius, M. R. Antonio, and J. H. Payer
Proc. - Electrochem. Soc. 94-29 (Corrosion and Reliability of Electronic Materials and Devices), 26-37 (1994)

In situ X-ray absorption fine structure studies of foreign metal ions in nickel hydrous oxide electrodes in alkaline electrolytes
S. Kim, D. A. Tryk, M. R. Antonio, R. Carr, and D. Scherson
J. Phys. Chem. 98 (40), 10269-76 (1994)

The oxidation state of cerium in Ce₂MoO₆
M. R. Antonio, J. S. Xue, and L. Soderholm
J. Alloys Compd. 207-208, 444-8 (1994)

Cerium valence in cerium-exchanged Preyssler's heteropolyanion through X-ray absorption near-edge structure
M. R. Antonio and L. Soderholm
Inorg. Chem. 33 (26), 5988-93 (1994)

Synthesis, structure and characterization of Ce_1-xA_xTiO₃ (0.0 < x < 0.8; A = strontium, barium)
J. E. Sunstrom, S. M. Kauzlarich, and M. R. Antonio
Chem. Mater. 5 (2), 182-91 (1993)

Applications of X-ray absorption fine structure to the in situ study of the effect of cobalt in nickel hydrous oxide electrodes for fuel cells and rechargeable batteries
S. Kim, D. A. Tryk, M. R. Antonio, and D. Scherson
Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem. 38 (4), 1457-63 (1993)

Silver ion coordination in membranes for facilitated olefin transport
M. R. Antonio and D. T. Tsou
Ind. Eng. Chem. Res. 32 (2), 273-8 (1993)

The oxidation state and coordination environment of chromium in a sealed anodic aluminum oxide film by x-ray absorption spectroscopy
J. S. Wainright, O. J. Murphy, and M. R. Antonio
Corros. Sci. 33 (2), 281-93 (1992)

Extended X-ray Absorption Fine Structure
M. R. Antonio
In Encyclopedia of Materials Characterization: Surfaces, Interfaces, Thin Films, edited by C. R. Brundle, C. A. Evans, Jr and S. Wilson (Butterworth-Heinemann, Boston, 1992), pp. 214-226

In situ XANES of an iron porphyrin irreversibly adsorbed on an electrode surface
S. Kim, I. T. Bae, M. Sandifer, P. N. Ross, R. Carr, J. Woicik, M. R. Antonio, and D. A. Scherson
J. Am. Chem. Soc. 113 (24), 9063-6 (1991)

Coordination and valence of niobium in titanium dioxide-niobium dioxide solid solutions through x-ray absorption spectroscopy
M. R. Antonio, I. Song, and H. Yamada
J. Solid State Chem. 93 (1), 183-92 (1991)

The chemistry of the thermal decomposition of pseudobrookite ferrous titanium oxides
R. G. Teller, M. R. Antonio, A. E. Grau, M. Gueguin, and E. Kostiner
J. Solid State Chem. 88 (2), 351-67 (1990)

Structural analysis of metastable pseudobrookite ferrous titanium oxides with neutron diffraction and Mössbauer spectroscopy
R. G. Teller, M. R. Antonio, A. E. Grau, M. Gueguin, and E. Kostiner
J. Solid State Chem. 88 (2), 334-50 (1990)

Structural environments and oxidation states of metal cations in bismuth cerium molybdate solid solutions by x-ray absorption spectroscopy
M. R. Antonio, J. F. Brazdil, L. C. Glaeser, M. Mehicic, and R. G. Teller
J. Phys. Chem. 92 (8), 2338-45 (1988)

Structural characterization of bismuth molybdates by x-ray absorption spectroscopy and powder neutron diffraction profile analysis
M. R. Antonio, R. G. Teller, D. R. Sandstrom, M. Mehicic, and J. F. Brazdil
J. Phys. Chem. 92 (10), 2939-44 (1988)

Interlayer coordination environments of iron, cobalt, and nickel in vanadyl phosphate dihydrate, VOPO₄•2H₂O, intercalation compounds
M. R. Antonio, R. L. Barbour, and P. R. Blum
Inorg. Chem. 26 (8), 1235-43 (1987)

New materials synthesis: characterization of some metal-doped antimony oxides
R. G. Teller, M. R. Antonio, J. F. Brazdil, and R. K. Grasselli
J. Solid State Chem. 64 (3), 249-60 (1986)

Stabilization of high-temperature antimony oxide with molybdenum incorporation. Structure of molybdenum-doped antimony oxide (Sb₂O₄) by powder neutron diffraction and extended x-ray absorption fine structure spectroscopy
R. G. Teller, M. R. Antonio, J. F. Brazdil, M. Mehicic, and R. K. Grasselli
Inorg. Chem. 24 (21), 3370-5 (1985)

Tungsten as a weak backscatter: an example of information loss in extended X-ray absorption fine structure (EXAFS) spectroscopy. Tungsten and iron EXAFS studies of tungsten-iron-sulfur clusters containing the WS₂Fe unit
M. R. Antonio, B. K. Teo, and B. A. Averill
J. Am. Chem. Soc. 107 (12), 3583-90 (1985)

Molybdenum K-edge extended X-ray absorption fine structure studies of synthetic molybdenum-iron-sulfur clusters containing the MoS₄ unit: development of a fine adjustment technique based on models
B. K. Teo, M. R. Antonio, and B. A. Averill
J. Am. Chem. Soc. 105 (12), 3751-62 (1983)

EXAFS model for the iron-molybdenum cofactor of nitrogenase: molybdenum, tungsten, and iron EXAFS of the [Cl₂FeS₂MS₂FeCl₂]^2- (M = molybdenum or tungsten) dianions. A comparison with the Mo EXAFS of nitrogenase
B. K. Teo, M. R. Antonio, D. Coucouvanis, E. D. Simhon, and P. P. Stremple
J. Am. Chem. Soc. 105 (18), 5767-70 (1983)

EXAFS of glassy metallic alloys: amorphous and crystalline molybdenum-nickel (MoNi)
B. K. Teo, H. S. Chen, R. Wang, and M. R. Antonio
J. Non-Cryst. Solids 58 (2-3), 249-74 (1983)

Intercalation of tetrathiafulvalene, tetrathiatetracene, and related molecules into iron oxychloride
B. A. Averill, S. M. Kauzlarich, and M. R. Antonio
J. Phys., Colloq. (C3, Colloq. Int. CNRS Phys. Chim. Met. Synth. Org., 1982),
1373-6 (1983)

Iron and molybdenum extended x-ray absorption fine structure studies of double-cubane clusters containing molybdenum iron sulfide (MoFe₃S₄) cores
M. R. Antonio, B. K. Teo, W. E. Cleland, and B. A. Averill
J. Am. Chem. Soc. 105 (11), 3477-84 (1983)

New EXAFS models for the iron sites of the iron-molybdenum cofactor in nitrogenase: the [(p-CH₃C₆H₄S)₂FeS₂FeS₂MoS₂]^3- trianion and the [(C₆H₅O)₂FeS₂MoS₂]^2- dianion
B. K. Teo, M. R. Antonio, R. H. Tieckelmann, H. C. Silvis, and B. A. Averill
J. Am. Chem. Soc. 104 (22), 6126-9 (1982)

Core dimensions in the 3Fe cluster of Desulfovibrio gigas ferredoxin II by extended X-ray absorption fine structure spectroscopy
M. R. Antonio, B. A. Averill, I. Moura, J. J. G. Moura, W. H. Orme-Johnson, B. K. Teo, and A. V. Xavier
J. Biol. Chem. 257 (12), 6646-9 (1982)

Iron EXAFS of the iron-molybdenum cofactor of nitrogenase
M. R. Antonio, B. K. Teo, W. H. Orme-Johnson, M. J. Nelson, S. E. Groh, P. A. Lindahl, S. M. Kauzlarich, and B. A. Averill
J. Am. Chem. Soc. 104 (17), 4703-5 (1982)

Intercalation of tetrathiafulvalene into iron oxychloride
M. R. Antonio and B. A. Averill
J. Chem. Soc., Chem. Commun. (8), 382-3 (1981)

Mark Antonio
Chemical Sciences & Engineering Division
Argonne National Laboratory, Bldg. 200
9700 South Cass Avenue
Argonne, IL 60439-4831, USA
Phone: 630/252-9267, fax: 630/252-4225, e-mail: mantonio@anl.gov