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Atmospheric Aerosol Chemistry

Ionic map of atmospheric particles enriched in sulfate (green) and methane sulfonate (blue) typical for a marine environment
Ionic map of atmospheric particles enriched in sulfate (green) and methane sulfonate (blue) typical for a marine environment

Atmospheric aerosols play an important role in global climate change. Variations of aerosols are recognized as a significant forcing factor that alters the planetary radiation balance onto and away from the Earth, thus contributing to global temperature change. The effects of climate forcing caused by aerosols are not well understood, especially in the case of anthropogenic aerosols. Indeed, the effect of aerosols has been one of the greatest sources of uncertainty in efforts to interpret climate change that occurred in the past century and to project future climate change.

This science theme is designed to advance the state of knowledge of aerosol physics and chemistry from the molecular level to regional and global scales and their impacts on climate change. State-of-the-art instrumentation at EMSL will be used to characterize the size, composition, density, morphology, chemical reactivity, and cloud interactions of aerosol particles. The research will employ a collaborative, comprehensive, and interdisciplinary approach that will combine both the unique analytical capabilities of EMSL and the research expertise of EMSL scientific staff and the user community.

This science theme is formulated around the following specific, key scientific topical areas that the aerosol chemistry and atmospheric science communities face today and will continue to face in the future:

Understanding the role of aerosols in climate change is an important scientific challenge that is critical to more accurately predict the environmental impact of future energy technology options. This science theme addresses the chemical and physical properties of organic aerosols that are of key relevance to cloud formation and climate change. Aerosols are constantly evolving, and the changes they undergo profoundly alter their impact and even how long they live or how far they travel. Providing the scientific foundation to better predict how and when these properties change is necessary so policy makers can make environmentally sound decisions about process that generate aerosols.

  1. Chemical Speciation of Sulfur in Marine Cloud Droplets and Particles: Analysis of Individual Particles from the Marine Boundary Layer Over the California Current.
  2. Kinetics of Heterogeneous Reaction of CaCO3 Particles with Gaseous HNO3 Over a Wide Range of Humidity.
  3. Simultaneous Measurements of Individual Ambient Particles Size, Composition, Effective Density, and Hygroscopicity.
  4. On Reflectance Ratios and Aerosol Optical Depth Retrieval in the Presence of Cumulus Clouds .
  5. Fabrication of SiO2 Microdisk Arrays for Optics and Light Trapping Experiments.

Atmospheric Aerosol Chemistry Capabilities Available at EMSL

Instrument Contact
Analytical: Chromatograph: Ion Wietsma, Tom
Analytical: Inductively Coupled Plasma-Mass Spec (ICP-MS) Wietsma, Tom
Analytical: Total Organic Carbon Analyzer (TOC) Wietsma, Tom
Analytical: Chromatograph: Gas/Mass Spec System 2005 Wietsma, Tom
Analytical: Chromatograph: Liquid Wietsma, Tom
Computing: Altix1 cluster Vorpagel, Erich
Computing: Chinook (HP 2310-Node Linux Cluster) Vorpagel, Erich
Computing: Data File Storage (NWfs) Cowley, David E
Wright, Ryan
Computing: SGI 16-processor Graphics Server (nwvisus) Vorpagel, Erich
Computing: Spokane cluster Bylaska, Eric
Rosso, Kevin M.
Electron Microscope: Scanning, Environmental, Field Emission (FEI) Laskin, Alexander
Electron Microscope: Scanning, Field Emission (LEO) Arey, Bruce
Electron Microscope: Transmission, High Resolution Wang, Chongmin
Electron Microscope: Dual-Beam FIB/SEM Arey, Bruce
Saraf, Lax
Electron Microscope: Transmission, CRYO 2005 Dohnalkova, Alice
Electron Spectrometer: Auger/Scanning Auger Lea, Scott
Electron Spectrometer: Scanning Multiprobe Surface Analysis System - Versaprobe Engelhard, Mark
Electron Spectrometer: XPS High Resolution (Quantum) Engelhard, Mark
Ion Accelerator, Beam Lines, and End Stations Shutthanandan, Shuttha
Mass Spectrometer: Laser Desorption - Ion Trap Alexander, M Lizabeth
Mass Spectrometer: Aerosol - time-of-flight Alexander, M Lizabeth
Mass Spectrometer: Isotope Ratio Alexander, M Lizabeth
Mass Spectrometer: Linear Ion Trap Quadrupole (LTQ) Orbitrap MS - for environmental research Laskin, Alexander
Mass Spectrometer: Single Particle -(SPLAT II) Zelenyuk, Alla
Microscope: Raman Confocal Hess, Nancy J.
Microscope: Scanning Probe - DI Nanoscope IIIa Multimode Lea, Scott
NMR Spectrometer: 2 Tesla Horizontal Bore Varian Unity Plus (Imaging) Ford,Joseph J
Minard, Kevin R
Proton Transfer Reaction Mass Spec(PTRMS) Alexander, M Lizabeth
Spectrometer: FTIR - HR Blake, Tom
Spectrometer: FTIR - standard Gassman, Paul
Johnson, Tim
Spectroscopy: Fluorescence, time-resolved Wang, Zheming
X-ray Diffraction: microbeam Nachimuthu, Ponnusamy