Office of Science
FAQ
Capabilities

Analytical: Total Organic Carbon Analyzer (TOC)

Quick Specs

  • Analytes: TC, IC, TOC, NPOC, and POC.
  • Method: Combustion/non-dispersive infrared gas analysis method
  • Combustion temperature: 680°C
  • Measuring range: 4 ppb to 4000 ppm TOC (to 5000 ppm for IC, to 400 ppm for POC)
  • Sample injection volume: 4 to 2000 μL

SSM-5000A Solid Sample Module

  • Analyte: TC, IC, TOC ( = TC - IC)
  • Method: TC: Catalytically aided combustion oxidation at 900°C
    IC: Pre-acidification, oven temperature 250°C
  • Measuring range: TC: 0.1 mg to 30 mg carbon
    IC: 0.1 mg to 20 mg carbon
  • Sample amount: 1 g (aqueous content < 0.5 g)

The carbon analyzer is used to analyze total carbon (TC), inorganic carbon (IC), total organic carbon (TOC), purgeable organic carbon (POC), and non-purgeable organic carbon (NPOC) in solid or liquid samples.

The system comprises a Shimadzu TOC-5000A TOC analyzer, a Shimadzu ASI-5000A autosampler, and a Shimdazu SSM-5000A solid sample module. The TOC-5000A has ultralow sensitivity and measures from 4 ppb to 4000 ppm of total carbon and 4 ppb to 5000 ppm of inorganic carbon. This instrument meets the needs of ultrapure industries, research facilities, and high salt requirements of marine users. SSM-5000A Solid Sample Module details follow.

Sample Preparation and Options

The laboratory that houses this instrument contains the necessary support items for sample preparation, including auto pipettes, a balance, nanopure water, and numerous calibration standards. All work with this instrument and within the associated laboratory must be performed in compliance with EMSL practices and permits.

Individuals may use this instrument independently for their research following the necessary training.

 

 

  1. Mechanisms controlling soil carbon turnover and their potential application for enhancing carbon sequestration .
  2. Comparing metal leaching and toxicity from high pH, low pH, and high ammonia fly ash.
  3. Uranium immobilization by sulfate-reducing biofilms grown on hematite, dolomite, and calcite.
  4. Reoxidation of Reduced Uranium with Iron(III) (Hydr)Oxides under Sulfate-Reducing Conditions.
  5. Diversity of Contaminant Reduction Reactions by Zero-Valent Iron: Role of the Reductate.
Wietsma, Tom | , 509-371-6375