Technology at a Glance

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Technology at a Glance

AT A GLANCE
Fall 2001

Technology at a Glance is a quarterly newsletter from the National Institute of Standards and Technology reporting on research results, funding programs, and manufacturing extension and technology services. If you have comments or general questions about this newsletter or if you would like to receive the four-page, color newsletter in hard copy, please email your mailing address to Gail Porter, editor, or call (301) 975-3392. About Technology at a Glance.

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ARTICLES
Ultrathin Wires Made Defect-free

Colorized transmission electron micrograph showing a cross-section through three trenches formed in a polymer substrate (light yellow areas) that are fully filled with copper. The green and red features of the central trench indicate an innocuous crystal defects within a cooper trench.NIST researchers have learned how to deposit defect-free copper wires into the ever-thinner and ever-deeper trenches that will traverse the multi-tiered real estate of future integrated circuits. The research may well produce a “model answer” for an industry-identified problem with no known solution that many experts in the field see looming in the coming years.

Today’s state-of-the-art computer chip includes several layers of copper “wiring” for on-chip electrical connections. To save space on the chip, the copper wires have been made narrow, with a height that is greater than the width. However, as the width of interconnects narrows from today’s 150 nm to about 65 nm by 2010, and as height to width ratios almost double, the process becomes increasingly prone to voids in the copper wires.

A team of NIST metallurgists and electrochemists has devised a copper-plating bath that can produce quality copper interconnects with the same trench-filling behavior as industry’s proprietary systems. This has enabled the team to unravel the details of the electrochemistry process known as “superfilling,” which allows tall, skinny wires to be produced defect-free. Understanding the process is key to creating future multi-level copper interconnects that are free of current-disrupting voids and seams.

The colorized transmission electron micrograph above shows a cross-section through three trenches formed in a polymer substrate (light yellow areas) that are fully filled with copper. The green and red features of the central trench indicate an innocuous crystal defect in the metal.

In addition, the team has developed a simple copper deposition computer model, which is helping industry determine optimum ranges for processing parameters in fabricating the wires. The NIST model can predict how different combinations of electroplating additives influence the electrodeposition of copper into confined geometries, such as trenches and vertical connections. Furthermore, the model can be used to predict the extendibility of copper electrodeposition in production of the ever-finer wiring of the future.

An overview of this project can be found at www.eeel.nist.gov/omp/interconnect.html.

Contact: Thomas Moffat, (301) 975-2143.

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Composite Pipes Carry Oil and Gas

In the Gulf of Mexico and other parts of North America, oil and gas are being transported through lightweight, corrosion-resistant pipes made of composite materials instead of metals, a cost-saving innovation that took many years and many hands to achieve.Composite Pipes

Composites—combinations of materials, usually reinforced with high-performance fiber—are difficult to produce economically and with the right characteristics for structural applications. Five companies, a university, and a research foundation finally achieved the necessary combination of materials and processing advances in a five-year research project co-funded by NIST’s Advanced Technology Program. The project was led by Hydril Co. of Houston, Texas.

The composite pipe (also called spoolable tubing) consists of a thermoplastic lining coated with epoxy reinforced by carbon and glass fibers. To make the pipe, the research team developed reliable, economical filament winding/ manufacturing technology believed to be unique; perhaps the largest database of composite characterization data in the industry; a resin curing system and patented in-line cure monitor; and predictive design software.

Among the most important technical achievements was the development of a raw materials characterization database, which includes data on the interaction of various combinations of materials, and an analytical methodology for predicting the performance of products produced reliably and repeatedly. This combination of advances enables the design of tubular components that can be stored on spools.

Another key innovation was the development of cost-effective manufacturing technology, including identification of the critical parameters that need to be controlled.

More than 61,000 meters (200,000 feet) of the pipe have been installed for 20 customers in four states and Canada. The pipe is used, for example, as liners to rehabilitate out-of-service pipelines. In addition to its light weight and corrosion resistance, the composite pipe typically costs much less than alternatives on an installed basis. Other benefits include resistance to chemical damage and fouling and reductions in the number of required connections and fittings.

Contact: Bill Stringfellow, (713) 941-6639 ext. 131.

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Atomic Clock Uses Optical Frequency

NIST researchers have demonstrated a new kind of atomic clock that has the potential to be up to 1,000 times more accurate than today’s best clock. They reported the findings in July on Sciencexpress (www.sciencexpress.org), an online publication of Science magazine.

Today’s international time and frequency standards measure a microwave frequency atomic resonance of about 9 billion cycles per second. By contrast, the new NIST device monitors an optical frequency more than 100,000 times higher, or about one quadrillion cycles per second.

The new clock is based on an energy transition in a single trapped mercury ion (a mercury atom that is missing one electron). Building a clock based on such a high-frequency transition was previously impractical because it requires both “capturing” the ion and holding it very still to get accurate readings, and having a mechanism that can “count” the ticks accurately at such a high frequency.

Precise timekeeping underlies much of the structure of modern civilization, including navigation, electric power management, and communications. It also has made possible significant advances in astronomy and physics. Today, the best clocks are based on a natural atomic resonance of the cesium atom—the atomic equivalent of a pendulum. For example, NIST-F1, one of the world’s most accurate time standards, is based on a microwave frequency and neither gains nor loses a second in 20 million years.

How good a clock is depends on stability and accuracy—whether the clock provides a constant, unchanging output frequency, and how close the measured frequency is to the fundamental atomic resonance that provides the clock’s “tick.” One advantage of the new clock based on the optical frequency is that it ticks much faster.

Contact: Scott Diddams, (303) 497-7459, sdiddams@boulder.nist.gov.

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Corrective Lenses For UV Lithography

NIST researchers have uncovered a potentially serious optical problem affecting designs for future generations of semiconductor manufacturing equipment using deep ultraviolet light. Current state-of-the-art production processes for semiconductor chips use deep ultraviolet lasers to image circuits with critical features as small as 130 nm. The next major steps for lithography are expected to be systems using even shorter wavelength light, ultimately achieving feature sizes in the range of 70 nm.

Some of the optics for current semiconductor production and all of the optics for future generation semiconductor lithography are made of calcium fluoride, one of only a few materials that are transparent at the shorter wavelengths of deep ultraviolet light. NIST physicists recently demonstrated experimentally that calcium fluoride crystals refract light differently depending on the polarization of the light. Calculations based on theory have confirmed the results.

Lithography equipment designers will have to account for this problem in the optics design and try to minimize its impact, for example, by combining particular relative orientations of the crystal axes of the various lenses. Commercial vendors are modifying lens design modeling software to include the effect on the system of the approximately 20 lenses present in a typical optical lithography tool. It is expected to be ready in October. NIST researchers are pursuing a potential solution involving mixed crystals to null the effect at the illumination wavelength.

Contact: John Burnett, (301) 975-2679.

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Designer Polymers To Aid Recycling

While it may look like a delicate tree drawn in the sand, the micrograph at right shows the beginning of a crystallization process as a new type of polymer is cooled down from its melt. The molecules of the polymer fold into flat, branch-like crystals that grow into the remaining amorphous liquid. Made with an atomic force microscope, the image is part of an effort by NIST materials researchers to help chemical manufacturers better understand how to tailor polymer blends to optimize specific properties like strength, toughness, and surface textures.The micrograph shows the beginning of a crystallization process as a new type of polymer is cooled down from its melt

Polyolefins made with metallocene catalysts are a versatile class of polymers that promises to help protect the environment while lowering the cost of structural plastics. Such materials are used in making bumpers for automobiles, as well as in many other applications. While previously used only in inexpensive “commodity” products, the use of improved catalysts for processing polyolefins now allows engineers to design these plastics with very specific chemical structures that improve strength, chemical stability, or other properties.

This makes polyolefins prime candidates for improving the proportion of plastics used in cars and trucks that can be recycled. The average car contains as many as 30 different types of plastic. Unlike the steel or aluminum in cars, the large number of different, incompatible plastics has made recycling these materials very difficult. NIST researchers hope that improving knowledge of polyolefin processing and properties will make it possible to use this one type of plastic for many auto parts, thereby substantially increasing the percentage of car materials that are lightweight and also can be recycled.

Contact: Charles Han, (301) 975-6772.

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Liaison Office Focuses on Autos

A newly organized NIST Industrial Liaison Office now is working to maximize the impact of NIST technical programs on industry. Currently, two pilot projects are ongoing, one looking at the health care industry and the other at the automotive industry.

Staff members for the Liaison Office will advise the NIST laboratories by getting feedback from current and potential automotive industry customers. They welcome suggestions and questions from automotive industry executives, managers, and engineers. They also are available to give presentations to auto industry groups on the NIST Automotive Project Portfolio, which currently contains more than 60 projects.

To help automotive industry personnel find appropriate technical assistance from NIST, the agency has posted a web page-www.nist.gov/automotive—providing convenient links to dozens of relevant research projects.

Contact: Clare Allocca, (301) 975-4359.

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New Guides Explain Europe’s Standards

Three newly-issued NIST guides to European Union directives on machinery, low-voltage equipment and electromagnetic compatibility can help U.S. manufacturers carry out the steps necessary to
demonstrate compliance with the EU-wide requirements and gain unfettered access to the
18-nation market. They are the first in a series of NIST-commissioned guides developed with the Commerce Department's International Trade Administration.

The easy-to-use introductory references are designed to acquaint businesses and government officials with the directives’ essential requirements and their relationship to other EU product safety laws. Each guide lists the types of products covered by the particular directive (as well as those that are excluded) and addresses issues regarding the treatment of components incorporated into market-ready products. In addition, the guides explain the hierarchy of EU, international, and national standards that might be used to satisfy the directives.

The new publications are available at: http://ts.nist.gov/ts/htdocs/210/gsig/eu-guides/sp951/sp951.htm.

Contact: Maureen Breitenberg, (301) 975-4031.

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SHORTS

Ferris Wheel Maker Rides High with MEP

Since introducing the first portable ferris wheel in 1900, the Eli Bridge Company of Jacksonville, Ill., has been providing the United States and the world with the rides many of us consider an essential part of summer. However, while the company takes great pride in the quality and modern craftsmanship of its manufacturing, the firm’s system for tracking costs and inventory was out-of-date and inefficient, costing the small company time and money. The company contacted the Illinois Manufacturing Extension Center, an affiliate of the NIST Manufacturing Extension Partnership. After assessing the company’s entire operation, IMEC specialists helped the company select and install a new software tracking system. As a result, Eli Bridge reduced costs by $100,000 and created five new jobs. Contact: Tucker Kennedy, (309) 677-4633, tkennedy@imec1.org.


Smarter Smoke Detectors

Cartoon by WelshBurning toast, shower steam, and dust—all common household occurrences—can set off an even greater annoyance, false smoke detector alarms. Too often, people disconnect their smoke detectors over these false alarms, depriving themselves of a potentially life-
saving early warning from an actual fire. NIST fire researchers are working with the Department of Housing and Urban Development on ways to end these false alarms. NIST researchers are studying sensor alarm thresholds to help manufacturers build “smarter” multi-sensor detectors that sound off only to real fire and smoke dangers. In the first part of the study, NIST researchers measured sensor responses to smoldering cotton, burning wood blocks, cigarette smoke, burning toast, dust, water vapor and smoke from heated cooking oil. Based on the data, they devised a formula that could serve as the basis for a combined carbon monoxide/smoke detector capable of distinguishing dangerous fire and smoke from normal, non-threatening activities. Contact: Tom Cleary, (301) 975-6858.


NIST Excels in Wine Testing

Cartoon by WelshNIST chemists recently demonstrated that their measurements of lead in wine are among the most accurate in the world. NIST was one of 14 National Measurement Institutes participating in an international pilot study of how accurately the official national standards agencies measure lead in wine. This study is one of many scientific measurement intercomparisons that are being conducted by the International Bureau of Weights and Measures. All participating institutes performed very well. They agreed very closely on the ultralow level of lead in the wine samples provided by the Institute for Reference Materials and Measurements in Geel, Belgium. NIST chemists made their exceptionally accurate measurements of the trace amounts of lead in the wine in a new Advanced Chemical Sciences Laboratory clean room facility in Gaithersburg, Md. The results of this study could help prevent measurement disagreements from becoming barriers to U.S. wine producers who wish to export their products overseas. Contact: John Fassett, (301) 975-4109.


“Black Box” Enhances Medical Decision Making

At a hospital in Indianapolis, the staff first learned that a patient had tuberculosis when a “black box” sent an alert to a pharmacist’s pager. Developed in part through a three-year project co-funded by the NIST’s Advanced Technology Program, the computerized decision-support system helped the staff isolate the highly contagious patient more quickly than was otherwise possible. The clinical alert system was developed by Sunquest Information Systems of Tucson, Ariz. Currently operating in seven hospital groups in six states, the alert system provides critical lab test results, adverse drug event monitoring data, and other information to medical staff by pager, e-mail, fax, or printer. It helps save money in a variety of ways, such as suggesting changes from intravenous to less expensive oral medications. Sunquest estimates that the alert system could save a hospital hundreds of thousands of dollars annually. Contact: Chris Mason, (801) 588-6020.

 

Co-Op CORNER

Abnormal Bleeding—A new procedure for treating abnormal uterine bleeding is a result of cooperative research between NIST and CryoGen Inc., of San Diego. The Food and Drug Administration recently approved the procedure, which uses a catheter based on NIST technology that can reach temperatures of -150 to -190 degrees Celsius at the tip. The catheter is inserted into the uterus where it freezes problem tissue. According to a review in Family Practice News, the treatment was successful in clinical trials, with patients typically discharged 30 minutes after the procedure and with nearly all returning to work the following day.

Contact: Ray Radebaugh, (303) 497-3710.


E-Business Testbed—Many smaller firms have been slow to use e-business tools. Confusion and lack of understanding about benefits, opportunities, and limitations of e-business are among the reasons. To help manufacturers better understand e-business and information technology strategies, NIST’s Manufacturing Extension Partnership is developing an e-Business Demonstration Testbed. The testbed will be used by MEP centers nationwide to demonstrate and simulate e-business applications. MEP is inviting companies to participate by providing commercial, off-the-shelf e-business Internet-based applications for improving communications, integrating the ordering process with enterprise resource planning and accounting, and transferring data within a supply chain.

For further information, go to www.mep.nist.gov/testbed-announcement or contact Rick Korchak, (301) 975-5020, TestbedManager@mep.nist.gov.


Non-linear Electronics—NIST and the University of Colorado at Boulder are planning a joint research center to support development of simulators and measurement systems for non-linear electronics in wireless communication systems. To maximize battery life in wireless devices, electronics engineers are using radio frequency power amplifiers in the non-linear regime (where output is not proportional to input). However, lack of adequate simulators and measurement systems have hampered design efforts. The new center will be supported by a consortium of companies with a common need for non-linear electronics measurement, modeling, and design tools. For further information, see www.boulder.nist.gov/nonlinear.

Contact: Don DeGroot, (303) 497-7212.

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About Technology at a Glance:

NIST is an agency of the US Department of Commerce's Technology Administration. NIST develops and promotes measurements, standards, and technology to enhance productivity, facilitate trade, and improve the quality of life. Technology at a Glance is produced by Public and Business Affairs, NIST, 100 Bureau Dr., Stop 3460, Gaithersburg, Md. 20899-3460. Any mention of commercial products is for information only; it does not imply recommendation or endorsement by NIST. Technology at a Glance Editor: Gail Porter, (301) 975-3392, email: gail.porter@nist.gov. For patent information, call (301) 975-3084.

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Created: 9/20/2001
Last updated: 11/9/2001
Contact: inquiries@nist.gov