Robowell: A reliable and accurate automated data-collection process applied
to reactive-wall monitoring at the Massachusetts Military Reservation, Cape
Cod, Massachusetts
by Gregory E. Granato and Kirk P. Smith
ABSTRACT
Robowell was developed and tested by the U.S. Geological Survey (USGS) to
automatically monitor ground-water quality. Robowell follows standard manual-sampling
protocols that require monitoring and recording of properties and constituents
in water pumped from a well or multilevel sampler until purge criteria have
been met. The Robowell process can be used to identify changes in ground-water
quality on a real-time basis without the cost of sample collection, processing,
and analysis. This automated process can be tailored for different applications.
Six Robowell units have reliably sampled water in different well designs
and geochemical environments during all four seasons of the year since 1994
to produce accurate real-time ground-water- quality records that are more
than 96 percent complete. Performance has been verified with a program of
regular quality-control samples obtained by using independent water-quality
probes, manual measurements, and laboratory analyses throughout the period
of record. Results of the quality-control program indicate that from 80 to
more than 95 percent of the measurements of specific-conductance, pH, and
dissolved-oxygen would be rated as good or better on the basis of draft USGS
guidelines for water-quality measurements. These results verify the integrity
of the automated-sampling records and demonstrate that the automated monitoring
system can accurately measure ground-water quality over a large range of geochemical
conditions.
A Robowell technology demonstration unit was installed and run on Cape Cod
at the Massachusetts Military Reservation with the assistance of the USGS
Toxic Substances Hydrology Research group. This unit was run to test the technology
and to monitor geochemical changes caused by emplacement of a zero-valent,
iron reactive wall designed to remediate volatile organic compounds in ground
water. The monitoring unit recorded substantial changes in ground?water quality
in a short period as the reaction byproducts of the wall and a subsequent
enzyme/pH adjustment raised pH by almost a full unit, raised specific conductance
by about 800 µS/cm (microsiemens per centimeter at 25 degrees Celsius), and
completely depleted the dissolved oxygen in water from the well. The automated
monitoring system demonstrated its success as a sentry well by notifying the
project chief through phone calls from a voice modem that geochemical changes
had been detected. Real-time records at the site define the variability in
ground-water quality during the monitoring period.