An instrumented slit die located
at the exit of a twin screw extruder allows in-situ optical measurements
of blend morphology and critical processing parameters. The combination
of in-line optical microscopy and light scattering probes a size range
from 0.1 microns to 100 microns. The facility has been used for the
study of polymer blends, reactive blends, in-situ fiber formation
and slippage.
The properties of a polymeric
material can frequently be enhanced by blending it with a second immiscible
polymer containing synergistic properties. An example is the blending
of rubber into nylon, in which a significant increase in impact strength
can be acheived. The final properties depend strongly on the morphology
of the dispersed phase.
The shear stress in the channel
has a profound effect on the morphology as seen in these three light
scattering (upper panel) / optical microscopy (panel) pairs. At low
shear (left side) , the disperesed phases is shperical. At intermediate
shear, long fibers of the dispersed phase form, parallel to the shear
direction. At higher shear (right side), the fibers break up into
ellipsoidal droplets.
Contact Information
Dr. Kalman Migler
Polymers Division
National Institute of Standards and Technology