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PMEL Programs and Plans
Accomplishments in FY 98 and Plans for FY 99

Carbon Dioxide Project


Carbon Dioxide Program

Accomplishments in FY 98

The decadal to centenial component of NOAA's Climate and Global Change (C&GC) Program addresses the need to assess and predict changes in climate on time scales of 10 to 100 years. One of the major components of this program concerns the climatic impact of the anthropogenic production of "greenhouse gases" such as carbon dioxide (CO2). CO2 is estimated to be responsible for roughly one-half of the "greenhouse gas" effect resulting from anthropogenic inputs of trace gases to the atmosphere. Because CO2 in the atmosphere absorbs long-wave radiation emitted from the earth's surface, the post-industrial increase of CO2 will have the effect of producing a higher equilibrium temperature of the troposphere. Credible prediction of the magnitude of this temperature increase is a high priority scientific issue. Recent model predictions suggest an increase of global mean surface temperature of 1.5-4.0°C in the next century for a doubling of atmospheric CO2. Future decisions on regulating emissions of "greenhouse gases" should be based on more accurate models which have been adequately tested against a well designed system of measurements. Predicting global climate change as a consequence of CO2 emissions requires coupled atmosphere/ocean/bioshpere carbon models that realistically estimate the rate of growth of CO2 in the atmosphere, as well as its removal, redistribution and storage in the oceans and terrestrial biosphere.

The primary objective of NOAA's Ocean Atmosphere Carbon Dioxide Exchange Study (OACES) is to quantitatively assess the fate of CO2 in the atmosphere and oceans. In order to accomplish this goal, the natural sources and sinks of carbon dioxide must be determined. During FY 98, the PMEL CO2 group determined the distribution of pCO2 in the equatorial Pacific during the 1997-98 ENSO event. Throughout the event pCO2 values showed a sharp decrease along the eastern edge of the warm pool which moved from west to east along the equator as the event developed. At the end of the ENSO event the Eastern Pacific abruptly moved into a strong La Niña phase beginning in May. Rapid increases in pCO2 (>600 µatm) were observed in the eastern Equatorial Pacific during this period.


Carbon Dioxide Program

Plans for FY 99

During FY 99, the Ocean-Atmosphere Carbon Exchange Study will provide data reduction and synthesis of the current field data in the Atlantic, Pacific and Indian Oceans, in collaboration with the participants of the DOE-CO2 Survey Science Team. In particular, the group will compare datasets with data obtained on other WOCE-WHP cruises and will provide internally consistent datasets encompassing roughly sixteen cruises in the Pacific Ocean, fifteen cruises in the Indian Ocean, and ten cruises in the Atlantic. These datas will be used by the modeling community for setting boundary conditions for general ocean circulation models, to determine the DIC inventory in each basin using several independent methods as outlined in Wallace (1995), and to estimate anthropogenic CO2 increases in the ocean Gruber et al., (1996) To facilitate comparisons of models and observations, the data will be gridded into similar box sizes as currently used in the models.

CO2 fluxes between air and water are poorly constrained because of lack of seasonal and geographic coverage of pCO2 (air-water disequilibrium) values and incomplete understanding of factors controlling the air-sea exchange. In addition to intensive monitoring of carbon parameters and parameters influencing pCO2 levels in surface water on dedicated cruises sponsored by OACES, PMEL, and AOML have outfitted the NOAA Ship Ka'imimoana with a new automated CO2 system to monitor surface water pCO2 on a continuous basis. While this effort has been a success we need more CO2 systems on NOAA ships to obtain the large area coverage. The new shipboard design, patterned after the systems recently built at AOML and PMEL, uses stop-flow technology to reduce the amount of gas required for analysis by the LICOR detector. It will be improved to facilitate fully autonomous operation. The improvements will include automating draining of water traps, comprehensive self diagnostics by the program running the computer, and automatic rebooting capabilities of the system if errors are detected. The underway system will be an integrated package for measurement of pCO2 in air and water and support sensors necessary to reduce the data (such as equilibrator temperature, location, salinity, sea surface temperature, and barometric pressure). The comprehensive automated package will facilitate operations on ships of opportunity. The NOAA Ship Ka'imimoana, used to maintain the TAO moorings on six month intervals, offers an excellent opportunity to determine seasonal and secular trends in the region.

In addition to this activity, we will continue our pCO2 instrument development activities with the group at MBARI, directed by Francisco Chavez, to provide a suite of chemical and biological sensors deployed on the 155W and 170W TAO mooring array in the equatorial Pacific in November 1997. The work leverages on developmental efforts carried out by MBARI (with support from NOAA, NASA, and PMEL) over the past several years. The primary objectives of this project are: (1) to determine the relationships between physical forcing, primary production and the exchange of carbon dioxide between ocean and atmosphere; (2) to determine the biological and chemical responses to climatic and ocean variability in the equatorial Pacific; (3) to determine the spatial, seasonal and interannual variability in primary production, carbon dioxide, and nutrient distributions; and (4) to determine the spatial, seasonal and interannual variability of sea surface pigment distributions to groundtruth sattelite measurements of ocean color.

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