FY 1988
The electron capture sulfur detector: Reduced sulfur species detection at the femtomole level
Johnson, J.E., and J.E. Lovelock
Anal. Chem., 60(8), 812–816 (1988) |
We have developed a new technique to detect reduced sulfur compounds by fluorination with F (at 200 ppm) on a heated Ag catalyst after GC separation. The excess F is removed by conversion to HF by reaction with H on a heated Pd catalyst. The fluorination product, presumably SF , is then detected in an electron capture detector (ECD). The Pd catalyst also destroys the response from halocarbons making the system sulfur specific. This ECD sulfur detector has a calculated minimum detectable level (MDL) for H S, OCS, CH SH, DMS, and CS of less than 2 fmol/s for each compound, 2 orders of magnitude lower than the best FPD systems. The ratio of the detected molar response of each of these sulfur compounds to the molar response of SF ranges from 2% to 20% and increases with increasing AgF temperature. |