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Chemistry Archive
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Magnesium and CO2
2/21/2005
name Todd
status educator
grade 9-12
location NV
Question - Is it possible to break up CO2 into its components by
introducing magnesium + heat to first produce 2MgO and C then scavenge
the O by bringing H2 in contact with the MgO + heat to produce Mg + H2O?
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DANGER. EXTREMELY HAZARDOUS. DO NOT TRY THIS UNDER ANY CIRCUMSTANCES.
Yes, burning Mg will reduce CO2 to C + 2MgO. However, this is a
pyrophoric reaction and extremely exothermic. As a result it is impossible
to extinguish a metal Mg fire with CO2. The only way is to use sand, which
just adds heat capacity to cool the fire below the ignition temperature.
Once the CO2 + Mg fire gets started side reactions with oxygen from the air
(and reaction with H2O vapor to produce H2, which then explodes).
Vince Calder
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