AkzoNobel Tb Aquatreat Biocides-1
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Published by Sharon Wilson
chemicals used in biocides for enhanced recovery in oil and gas.
chemicals used in biocides for enhanced recovery in oil and gas.
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Cost-effective, broad-spectrum biocides
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Aquatreat Biocides are EPA-registered, non-oxidizing dithiocarbamates that have a long history of proven performance. In cooling towers and airwashers, experience has shown that Aquatreat Biocides are effective in controlling both planktonic and sessile microorganisms. In paper mills, Aquatreat Biocides are known to be the most cost-effective materials available for the control of slime-forming bacteria and fungi in both virgin and recycle mills. For both beet and cane sugar mills, Aquatreat Biocides can be used to effectively control mesophilic and thermophilic bacteria that commonly foul the sugar production process. Aquatreat Biocides are especially effective in controlling sulfate-reducing bacteria in many
applications, including drilling uids and petroleum recovery waters.
Additional uses for Aquatreat Biocides include sapstain control, fuel
storage and in-ue gas desulfurization thickeners.
Performance Features
• EPA registered for a wide range of applications• Meet FDA requirements for use in paper and sugar applications• Cost effective• Effective against a broad spectrum of microorganisms, including
bacteria, fungi and algae: - Aerobic and anaerobic bacteria - Sulfate-reducing bacteria (SRB) - Yeasts and molds -
Legionella
• Compatibility and strong performance in a wide range of environments/
conditions - Broad pH and temperature stability - Organic loading
- Dissolved and suspended solids• Not persistent in discharge waters• Favorable handling and toxicity compared with competitive materials
Effective against a broad spectrum of microorganisms
Product Chemistry
Aquatreat Biocides are based on dithiocarbamate chemistry. Aquatreat
SDM (Figure 1) and Aquatreat KM (Figure 2) are single-component biocides
based on the sodium and potassium salts of dimethyldithiocarbamate.
Aquatreat DNM-9, Aquatreat DNM-30 and Aquatreat DNM-360 are dual-
component biocides based on a blend of sodium dimethyldithiocarbamate
and disodium ethylene-bis-dithiocarbamate (Figure 3). Aquatreat Biocides are applicable for a wide range of industrial uses. Table 1 summarizes
acceptable use patterns for these products.
Toxicology
Aquatreat Biocides have a low order of toxicity to humans. Tables 2 and 3 show comparative data for Aquatreat DNM-30 in eye and skin irritation
studies. Figures 4 and 5 show comparative oral and dermal toxicity
with Aquatreat DNM-30 and other commonly used biocides. Aquatreat Biocides are known to be toxic to sh and aquatic organisms. As with
any biocide, care must be taken to eliminate the possibility of release of Aquatreat Biocides into natural waterways such as lakes, streams, rivers
and oceans. Aquatreat products are not persistent biocides. Degradation
of the products occurs as a result of oxidation, sunlight, lower pH and microbial action.
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Biocide
Classication under
21 CFR 191.12
Aquatreat DNM-30Non-irritant
Isothiazolin
Corrosive
GluteraldehydeSevere Irritant
DBNPA
Severe Irritant
Biocide
Classication under
21 CFR 191.11
Aquatreat DNM-30Non-irritant
IsothiazolinSevere IrritantGluteraldehydeSevere Irritant
DBNPA
Severe Irritant
ProductCooling Towers Air WashersPulp & Paper MillsCane Sugar MillsBeet Sugar MillsDrilling FluidsHydro-Carbon FluidsPetroleum Recovery Sapstain Control
Aquatreat SDM••••••• Aquatreat KM•••• Aquatreat DNM-9••••••• Aquatreat DNM-30•••••••• Aquatreat DNM-360•••••••
Table 1:
Application use patterns
Aquatreat
®
SDM Aquatreat KMAquatreat DNM-9, DNM-30, DNM-360Figure 1:
Sodium Dimethyldithiocarbamate
Figure 2:
Potassium Dimethyldithiocarbamate
Figure 3:
Dual-Component Biocides
Figure 4:
Oral Toxicity - LD
50
Table 2:
Eye Irritation in Rabbits
Figure 5:
Dermal Toxicity - LD
50
Table 3:
Skin Irritation in Rabbits
16001400120010008006004002000
AQUATREAT DNM-30ISOTHIAZOLINGLUTERALDEHYDE
m g / k g
300025002000150010005000
m g / k g
AQUATREAT DNM-30ISOTHIAZOLINGLUTERALDEHYDE
H
3
CCH
3
S
-+
NaNSC
H
3
CCH
3
S
-+
K NC
H
3
CCH
3
S
-+
NaS
-+
NaS
-+
NaNNHHNSSSC
